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Copper scrap purity The conversion of carbon dioxide (CO2) into value-added chemicals such as ethanol is an important aspect of sustainable energy research. Metal-organic frameworks (MOFs), composed of metal centres and organic linkers, have attracted considerable attention for their potential as catalysts due to their high surface areas and tunable properties. In a recent study published in the journal Nature, a team of researchers led by the University of Cambridge have developed a MOF-based catalyst that can selectively convert CO2 into ethanol, a valuable fuel and chemical feedstock. The MOF used in this study, known as Cu(I)-BTC, contains copper centres that are able to activate CO2 molecules. However, the conversion of CO2 to ethanol typically requires multiple steps, including reduction and protonation, which can be energetically difficult and easy to destabilize. To overcome these challenges, the researchers used an innovative cooperative catalyst system, whereby multiple Cu(I) sites within the MOF work together to promote the necessary chemical transformations. By combining spectroscopic techniques and theoretical simulations, the researchers were able to gain a detailed understanding of the reaction mechanism involved. They found that a copper-carbonate intermediate plays a key role in catalyzing the reduction and protonation of CO2, with adjacent Cu(I) sites providing crucial stabilizing interactions. In addition to its high selectivity towards ethanol, the catalyst is also able to operate at low pressure and room temperature, reducing the energy requirements for the conversion process. Overall, these findings demonstrate the potential of MOF-based catalysts for sustainable energy production, and provide important insights into the development of selective and efficient catalytic systems for CO2 conversion Scrap metal reclaiming and recycling center Scrap copper pricing Copper machining waste recycling Scrap Copper wire Copper scrap purification Metal recycling and reclaiming center
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